A capacitive chemical sensor based on porous silicon for. To study the influence of porous silicon physical parameters, we have fabricated several layers, obtained by electrochemical etch in a hfetoh 3. Sep 22, 2005 macroporous silicon microcavities for detection of large biological molecules have been fabricated from highly doped n. Three different types of psi microcavities were produced. Coating the sensor internal surface with proteins of different sizes produces a different amount of resonance redshift. Macroporous silicon microcavities for detection of large biol. Photonic crystal sensors based on porous silicon mdpi. We present in this paper that porous silicon can be used as a large surface area matrix as well as the transducer of biomolecular interactions. We theoretically and experimentally demonstrate an ultra. Ntype macroporous silicon microcavity structures were prepared using electrochemical etching in an hf solution in the absence of light and. The structure and porosity of the matrixes were characterized by scanning force. Apr 09, 20 appropriately designed porous silicon cantor structures also showed higher sensitivity for the detection of silanization and further functionalization of the pore walls than porous silicon microcavities. High sensitivity detection of cdsezns quantum dotlabeled dna. Macroporous silicon in materials science within the scope of this work the macroporous silicon material system was used for a number of applications in the.
A chemical pathway is proposed to functionalize and stabilize porous silicon structures that are primordial for further effective molecular confinement. On chip protein preconcentration for enhancing the sensitivity of. Positive and negative anisotropy liquid crystals are investigated, leading to controllable tuning to both longer and shorter wavelengths. Porous silicon onedimensional photonic crystals for optical. Twodimensional silicon photonic crystal based biosensing platform for protein detection mindy lee and philippe m. Twodimensional silicon photonic crystal based biosensing. May 21, 2018 the presence of functional groups adsorbed on the surface of the synthesized. Stable porous silicon microcavities psimcs are designed in order to detect the confined glucose oxidase gox at low concentration. On chip protein preconcentration for enhancing the. Fabrication and characterization of macroporous silicon.
Macroporous silicon microcavities for macromolecule detection adv. Porous silicon microcavities psm optical crystals consisting of a fabryperot microcavity embedded between two distributed bragg reflectors have been fabricated by electrochemical etching. Macroporous silicon is a material which widely extends the traditional application areas of silicon from modern microelectronics to optoelectronics, microphotonics, micromechanics, sensorics, etc. Macroporous silicon fabrication max planck society. The psi waveguides were produced at different anodisation temperatures to reduce the interface roughness. The surface modification has been characterized by contact angle measurements. Hoover abstract macroporous silicon biochemical sensing devices have been developed, fabricated and tested. Development ofmacroporous silicon for biochemical sensing. The microcavities consist of porous silicon layers with alternating low and high porosity.
Macroporous silicon with its high perfectness represents an ideal 2d photonic crystal pc exhibiting novel properties for the propagat. Therefore, d ifferent techniques and procedures were used to achieve the required pore geometry or surface condition. Porous silicon microcavities for optical hydrocarbons detection. Development ofmacroporous silicon for biochemical sensing applications tiffany m.
Magnesiothermically formed porous silicon thin films on silicononinsulator optical microresonators for highsensitivity detection. Macroporous silicon porous materials are characterized by a large surfacetovolume ratio. Macroporous silicon is a material produced from silicon 100 single crystal wafers. One and twodimensional versions of these structures 1dphc, 2dphc can be readily fabricated using standard techniques from the microelectronics industry. Macroporous silicon microcavities for detection of large biological molecules have been fabricated from highly doped n. Macroporous silicon for photonic crystals in the ir. Appropriately designed porous silicon cantor structures also showed higher sensitivity for the detection of silanization and further functionalization of the pore walls than porous silicon microcavities.
The structure was obtained by electrochemical etching of crystalline silicon in a hfbased solution 50 wt. Enhanced excitonic emission efficiency in porous gan. Macroporous silicon for spectroscopic co2 detection. Optical characteristics and environmental pollutants. Macroporous silicon microcavities for macromolecule detection article in advanced functional materials 1511. The sensitivity of the prepared macroporous mirocavity structures depended on several parameters such as the pore size, the porosity contrast. Achieving sharp spectral resonances in porous silicon based photonic structures is of significant practical importance for improving the accuracy of refractive indexbased sensing in chemical and b. Identification of gram negative bacteria using nanoscale. Porous silicon psi nanomaterials have been widely studied as. Photonic crystals have opened new ways for the miniaturization of optical detector devices. In figure 9a a schematic and a sem image of a cantor structure etched into silicon are displayed. Fe 2 o 3 particles can be examined by fourier transform infrared ftir spectroscopy. Dec 10, 2008 read functionalization of nanostructured porous silicon microcavities for glucose oxidase detection, sensors and actuators b.
Examples for porous materials are zeolites, porous metalorganic frameworks, and aerogels. Macroporous silicon with its high perfectness represents an ideal 2d photonic crystal exhibiting novel properties for the propagation of infrared light inside. The porous silicon walls were lined with oxide and aluminum electrodes were placed on either side of the porous silicon membrane. Especially for ntype silicon this is nowadays a well known process. Porous silicon based resonant mirrors for biochemical sensing. Jul 15, 2014 read a capacitive chemical sensor based on porous silicon for detection of polar and nonpolar organic solvents, applied surface science on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Macroporous silicon microcavities for detection of large biological molecules have been fabricated from highly doped ntype silicon. Dna optical detection based on porous silicon technology. Abstract macroporous silicon microcavities for detection of large biological molecules have been fabricated from highly doped n. Macroporous silicon develops if silicon is anodically biased and electrochemically etched in hydrofluoric acid hf. Facile design and stabilization of a novel onedimensional. Bioconjugation of heavy metalbinding proteins on surface.
Coupling of surface waves in highly defined onedimensional porous silicon photonic crystals for gas sensing applications. We theoretically and experimentally demonstrate an ultrasensitive twodimensional photonic crystal microcavity biosensor. Scanning electron microscopy sem clearly depicted their physical sandwich construction. Microcavity based on macroporous silicon infiltrated with liquid crystals is described theoretically using the proposed model. Macroporous silicon microcavities for macromolecule detection advanced functional materials 1 septembre 2005 macroporous silicon microcavities for detection of large biological molecules have been. Pdf polarization dependence of optical characteristics of. Fauchet, macroporous silicon microcavity for macromolecule detection, adv. We report the fabrication of heavily doped ptype porous silicon with pore. Pdf polarization dependence of optical characteristics.
Welldefined controllable pore sizes up to 120 nm have been obtained by systematically optimizing the etching parameters. A carbon dioxide sensor based on a photonic crystal of macroporous silicon and measurements of its response are presented in this paper. Ouyang h, christophersen m, viard r, miller bl, fauchet pm 2005 macroporous silicon microcavities for macromolecule detection. Functionalization of nanostructured porous silicon. Optimising porous silicon bragg reflectors for narrow. Extinction ratios greater than 10 db have been demonstrated. Macroporous silicon microcavities for macromolecule. Jia pei, yanchun tang, ning xu, wei lu, shoujun xiao, jianning liu. Highly sensitive ethanol chemical sensor based on novel ag. Electrical and thermal modulation of porous silicon microcavities is demonstrated based on a change in the refractive index of liquid crystals infiltrated in the porous silicon matrix.
Osa electrical and thermal modulation of silicon photonic. Since the pore size is much smaller than the incident wavelength of light, each porous silicon layer is treated as an effective medium with a specific effective refractive index. Fluorescence measurements have been used to investigate the stability of the dna single strands bound to the nanostructured. The dependence of the sensor sensitivity on pore size is discussed. Planar silicon sensors, exemplified here by arrayed imaging reflectometry air. The device is fabricated on a silicononinsulator wafer and operates near its resonance at 1. Bruggeman effective medium approach for modelling optical properties of porous silicon. Jul 21, 2017 facile design and stabilization of a novel onedimensional silicon based photonic crystal microcavity. We report the fabrication of heavily doped ptype porous silicon with pore diameters that can be tuned, depending on the etching condition, from approximately 5 to 1200 nm. Oct 25, 2018 this paves the way for experimental investigations in the area of fundamental optics 4, or for realizing the lowcost advanced biosensors for detection of macromolecules in general 5, or, more. Covalently derivatized nta microarrays on porous silicon for multimode detection of histagged proteins. This paves the way for experimental investigations in the area of fundamental optics 4, or for realizing the lowcost advanced biosensors for detection of macromolecules in general 5, or, more. Another type of photonic structures socalled polybasic multilayers were suggested for the fabrication of highly sensitive porous silicon biosensors. We use construction of electrical contacts, which allows apply.
Macroporous silicon microcavities for macromolecule detection. Macroporous silicon microcavities for macromolecule detection h ouyang, m christophersen, r viard, bl miller, pm fauchet advanced functional materials 15 11, 18511859, 2005. This chapter focuses on a highly sensitive class of labelfree optical sensor. Porous silicon onedimensional 1d photonic crystal microcavities are fabricated as building blocks for optical modulators. Optical losses measurements were performed at 1550 nm on both porous silicon psi and oxidised psi opsi planar waveguides as a function of interface roughness. Silicon photonic crystal nanocavitycoupled waveguides for errorcorrected optical biosensing. Chemical on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. A photochemical functionalization process which passivates the porous silicon surface of optical biosensors has been optimized as a function of the thickness and the porosity of the devices.
1062 1373 217 229 1505 733 315 947 383 1199 140 1534 494 1264 630 314 1378 1224 242 180 500 1275 690 49 934 922 30 829 343 364 832 999 1202